Refining the interpretation of near-infrared band shapes in a polyynediyl molecular wire.

نویسندگان

  • Matthias Parthey
  • Josef B G Gluyas
  • Phil A Schauer
  • Dmitry S Yufit
  • Judith A K Howard
  • Martin Kaupp
  • Paul J Low
چکیده

Spinning to improve (band) shape: A blend of theoretical and experimental work demonstrates that the rotational conformation of mixed-valence complexes influences the low-energy (NIR) transitions in such molecules. Interpretations of the NIR band shapes are presented.

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عنوان ژورنال:
  • Chemistry

دوره 19 30  شماره 

صفحات  -

تاریخ انتشار 2013